D. Silica and . Meoh, Aspect: brown solid Rf value: 0

]. O. Norberg, L. Deng, M. Yan, O. Ramström, O. Ramström et al., Photo-Click Immobilization of Carbohydrates on Polymeric Surfaces???A Quick Method to Functionalize Surfaces for Biomolecular Recognition Studies, Bioconjugate Chemistry, vol.20, issue.12, pp.2364-2370, 2004.
DOI : 10.1021/bc9003519

]. G. Bernardes, E. J. Grayson, S. Thompson, J. M. Chalker, J. C. Errey et al., From Disulfide- to Thioether-Linked Glycoproteins, Angewandte Chemie International Edition, vol.15, issue.12, pp.2244-2247, 1993.
DOI : 10.1002/anie.200704381

S. David, Chimie moléculaire et supramoléculaire des sucres, 1995.

Y. M. Choy and A. M. Unrau, Simple, unambiguous syntheses of 2,3,6- and 2,4,6-tri-O-methyl-d-mannose., Carbohydrate Research, vol.17, issue.2, pp.439-443, 1971.
DOI : 10.1016/S0008-6215(00)82552-5

Q. Wang, J. Fu, and J. Zhang, A facile preparation of peracylated ??-aldopyranosyl chlorides with thionyl chloride and tin tetrachloride, Carbohydrate Research, vol.343, issue.17, pp.2989-2991, 2008.
DOI : 10.1016/j.carres.2008.08.037

H. J. Gabius, Animal lectins and life: a guided tour into the realm of the sugar code, Biochimica et Biophysica Acta (BBA) - General Subjects, vol.1572, issue.2-3, pp.163-164, 2002.
DOI : 10.1016/S0304-4165(02)00305-7

Z. Pei, R. Larsson, T. Aastrup, H. Anderson, J. Lehn et al., Quartz crystal microbalance bioaffinity sensor for rapid identification of glycosyldisulfide lectin inhibitors from a dynamic combinatorial library, Biosensors and Bioelectronics, vol.22, issue.1, pp.42-48, 2006.
DOI : 10.1016/j.bios.2005.11.024

URL : https://hal.archives-ouvertes.fr/hal-00123177

K. Jansson, G. Noori, and G. Magnusson, 2-(Trimethylsilyl)ethyl glycosides. Transformation into glycopyranosyl chlorides, The Journal of Organic Chemistry, vol.55, issue.10, pp.3181-3185, 1990.
DOI : 10.1021/jo00297a038

P. V. Murphy, J. L. O-'brien, and A. B. Smith, Stereospecific synthesis of ??-d-allopyranosides by dihydroxylation of ??-d-erythro-2,3-dideoxyhex-2-enopyranosides, Carbohydrate Research, vol.334, issue.4, pp.327-335, 2001.
DOI : 10.1016/S0008-6215(01)00181-1

P. G. Wang, Sugars synthesized in a snap, Nature Chemical Biology, vol.3, issue.6, pp.309-310, 2007.
DOI : 10.1016/S0040-4039(97)00006-3

H. Dong, Z. Pei, and O. Ramström, Stereospecific Ester Activation in Nitrite-Mediated Carbohydrate Epimerization, The Journal of Organic Chemistry, vol.71, issue.8, pp.3306-3309, 2006.
DOI : 10.1021/jo052662i

Z. Pei, H. Anderson, T. Aastrup, and O. Ranström, Study of real-time lectin???carbohydrate interactions on the surface of a quartz crystal microbalance, Biosensors and Bioelectronics, vol.21, issue.1, pp.60-66, 2005.
DOI : 10.1016/j.bios.2004.10.006

F. Batt, O. Piva, and F. Fache, Unexpected tosyl deprotection during osmium catalysed dihydroxylation, Tetrahedron Letters, vol.49, issue.3, pp.566-568, 2008.
DOI : 10.1016/j.tetlet.2007.11.058

G. D. Vite and T. A. Spencer, Exploration of a novel cyclization reaction. Synthesis of (.+-.)-.beta.-eudesmol, The Journal of Organic Chemistry, vol.53, issue.11, pp.2555-2560, 1988.
DOI : 10.1021/jo00246a029

M. Sridhar, B. A. Kumar, and R. Narender, Expedient and simple method for regeneration of alcohols from toluenesulfonates using Mg???MeOH, Tetrahedron Letters, vol.39, issue.18, pp.2847-2850, 1998.
DOI : 10.1016/S0040-4039(98)00314-1

T. W. Greene and P. G. Wuts, Protective Groups in Organic Synthesis, 2007.
DOI : 10.1002/0471220574

G. Adiwidjaja, J. S. Brunck, K. Polchow, and J. Voss, Preparation of methyl 2,3-di-O-mesyl-4,6-thioanhydro-??-d-galactopyranoside and methyl 2-O-mesyl-4,6-thioanhydro-??-d-gulopyranoside, Carbohydrate Research, vol.325, issue.4, pp.237-244, 2000.
DOI : 10.1016/S0008-6215(00)00009-4

R. Rosseto, N. Bibak, R. Deocampo, T. Shah, A. Gabrielan et al., -Toluenesulfonate for Hydroxyl Group Protection, The Journal of Organic Chemistry, vol.72, issue.5, pp.1691-1698, 2007.
DOI : 10.1021/jo062352f

URL : https://hal.archives-ouvertes.fr/hal-01140442

I. Hamachi, T. Nagae, S. Shinkai, and J. , A General Semisynthetic Method for Fluorescent Saccharide-Biosensors Based on a Lectin, Journal of the American Chemical Society, vol.122, issue.48, pp.12065-12066, 2000.
DOI : 10.1021/ja002044d

K. Pachamuthu and R. R. Schmidt, Synthetic Routes to Thiooligosaccharides and Thioglycopeptides, Chemical Reviews, vol.106, issue.1, pp.160-187, 2006.
DOI : 10.1021/cr040660c

T. Ogawa, K. Beppu, and S. Nakabayashi, Trimethylsilyl trifluoromethanesulfonate as an effective catalyst for glycoside synthesis, Carbohydrate Research, vol.93, issue.1, pp.6-9, 1981.
DOI : 10.1016/S0008-6215(00)80765-X

R. K. Jain, X. Liu, S. R. Oruganti, E. V. Candrasekaran, and K. L. Matta, Synthesis of oligosaccharide substrates for N-linked glycoprotein processing enzymes, Carbohydrate Research, vol.271, issue.2, pp.185-196, 1995.
DOI : 10.1016/0008-6215(95)00073-3

D. Crich and M. Smith, 1-Benzenesulfinyl Piperidine/Trifluoromethanesulfonic Anhydride:?? A Potent Combination of Shelf-Stable Reagents for the Low-Temperature Conversion of Thioglycosides to Glycosyl Triflates and for the Formation of Diverse Glycosidic Linkages, Journal of the American Chemical Society, vol.123, issue.37, pp.9015-9020, 2001.
DOI : 10.1021/ja0111481

H. H. Jensen, C. M. Pedersen, and M. Bols, Going to Extremes: ???Super??? Armed Glycosyl Donors in Glycosylation Chemistry, Chemistry - A European Journal, vol.115, issue.27, pp.7576-7582, 2007.
DOI : 10.1002/chem.200700947

X. Geng, V. Y. Dudkin, M. Mandal, and S. J. Danishefsky, In Pursuit of Carbohydrate-Based HIV Vaccines, Part 2: The Total Synthesis of High-Mannose-Type gp120 Fragments???Evaluation of Strategies Directed to Maximal Convergence, Angewandte Chemie International Edition, vol.43, issue.19, pp.2562-2565, 2004.
DOI : 10.1002/anie.200353626

Y. Pei, H. Yu, Z. Pei, M. Theurer, C. Ammer et al., Photoderivatized Polymer Thin Films at Quartz Crystal Microbalance Surfaces:?? Sensors for Carbohydrate???Protein Interactions, Analytical Chemistry, vol.79, issue.18, pp.6897-6902, 2007.
DOI : 10.1021/ac070740r

H. Driguez, Thiooligosaccharides as Tools for Structural Biology, ChemBioChem, vol.18, issue.5, pp.311-318, 2001.
DOI : 10.1002/1439-7633(20010504)2:5<311::AID-CBIC311>3.0.CO;2-L

URL : https://hal.archives-ouvertes.fr/hal-00307672